I am working on a VM that is running GNOME under RHEL 7 and I typically run with 12 workspaces. The default GNOME install only has the keyboard shortcut configurations up to “Switch to workspace 4”.
It turns out that the solutions is to use the gsettings cli tool to add additional shorcuts.
$ gsettings set org.gnome.desktop.wm.keybindings switch-to-workspace-5 "[\"<Control>F5\"]"
$ gsettings set org.gnome.desktop.wm.keybindings move-to-workspace-5 "[\"<Alt>5\"]"